Point mutations in the active site were found to decrease or increase enantioselectivity. The acyl chain length was shown to affect enantioselectivity in transesterifications of a sec-alcohol. Molecular modeling of the spatial freedom of the enzyme-substrate transition state indicated correlation tothe transition state entropy. Resolution of 1-bromo-2-butanol revealed non-steric interactions to influence both Δ R-SΔ H ‡ and Δ R-SΔ S ‡. 3-Hexanol was an exception where the preferred enantiomer was favored both by enthalpy and by entropy. Generally the two terms were counteracting, meaning that the enantiomer favored by enthalpy was disfavored by entropy. The contribution of enthalpy, Δ R-SΔ H ‡, and entropy, TΔ R-SΔ S ‡, to the differential free energy, Δ R-SΔ G ‡, of kinetic resolutions of sec-alcohols were of similar magnitude. In the present investigation the influence of substrate structure, variations on enzyme structure and of reaction media on the enantioselectivity of Candida Antarctica lipase B has been studied. Determination of the temperature dependence of enzyme enantioselectivity allows for thermodynamic analyses that reveal the contribution of differential activation enthalpy, Δ R-SΔ H ‡, and entropy, Δ R-SΔ S ‡. Enantioselectivity is a particularly attractive enzyme property, which is utilized for the production of enantiopure substances. 2001 (English) Doctoral thesis, comprehensive summary (Other scientific) Abstract īiocatalysis has become a popular technique in organic synthesis due to high activity and selectivity of enzyme catalyzed reactions.
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The Chinese government can always come up with ways to access user data stored by Chinese companies. WeChat is owned by a private entity, Tencent, but remember that it’s a Chinese company. Instead, WeChat uses transport encryption, which allows users as well as WeChat itself to access your data. This means conversations between two users aren’t private. Unlike other popular messaging apps, WeChat lacks end-to-end encryption. It offers poor security and has a terrible privacy policy. If you find someone, share your verification code and you’re done. That being said, some messages might not receive a response at all.Īn unconventional way of getting WeChat approval is reaching out to generous folks on online forums like Reddit, asking them if they’re willing to verify your WeChat account. Users report that contacting the support team in Chinese is helpful, but messages sent in English take more time to receive a response. However, in some cases, users have reported that contacting the WeChat support team helps. Have a WeChat user scan the QR code to complete registration. Unfortunately, unless you complete this process, there’s a very slim chance that you’ll be able to access WeChat. Once you do find someone, you’ll need to provide them with your QR code so they can verify you. Finding a China Mainland user might be hard for an international user, but it helps. Nobody knows why WeChat declines some accounts even after verification, but to maximize your chances of approval, see if you can find a friend based in Mainland China to verify your account. Note that WeChat might decline activating your account even if all conditions are met.
Almost instantly by looking at the available controls you can see how to use it and it works in practice just as you think it would from the available controls.Īs far as first impressions go I got nothing less than I expected Included Bundle Removing it from the box the appearance is black with the display silent with a mirror black "piano" finish and the keys a gleaming pearl white. The keyboard is well packaged in the box with support foam under the keys and sturdy foam ends able to protect the device well during shipping. The build quality is excellent with glossy soft keys, brushed aluminium top and a minimal appearance leaving the keyboard looking simple and inviting. To start with plain and simple this is a good looking keyboard! Forget the flashy light guide or fancy touch strips, the keyboard looks quality in all the images you see and I was just as impressed when I first pulled it out of the box. Pitch/Mod touch strips with advanced programming options.Advanced Host Integration (control transport and track navigation). Auto mapping for all Komplete instrument patches.16 banks of encoders for each preset/template.High resolution VFD display for each encoder.8 programmable touch sensitive endless encoders.Unified browsing of Komplete 9/10 Instruments using keyboard.Free Komplete Elements pack for non-Komplete users.25 \ 49 \ 61 \ 88 Key versions available.Pros: Tightly integrates with Komplete 10 Instruments, Simple to learn, Impressive featuresĬons: Not simple to browse 3rd party presets, Concerns over encoder quality, Noisy keybed I am also reviewing the 1.5 version of software which now adds the ability to load and control VST instruments. The 88 key version has the same controls again but a different keybed aimed more at the piano players. I will be reviewing the S61 version of the keyboard which offers the same options/controls as the 25/49 key versions. Please see our Amazon Global Store Returns policy and Refunds policy for more information about returning Amazon Global Store items.Ĭamera, Electronics and PC Returns Policy Please see About Marketplace Returns & Refunds for details on Seller returns policies. To return faulty items see our Returning Faulty Items policy.įor items ordered on from a seller that fulfils and ships its own inventory (also called a third party seller), any returns will be in accordance with the returns policy set by that seller (not the Amazon AU returns policies). This change of mind return policy is in addition to, and does not affect your rights under the Australian Consumer Law including any rights you may have in respect of faulty items. Unless otherwise stated, original shipping fees for change of mind returns are not refunded. Please Contact Us and see About Items That Can’t Be Returned. In some circumstances, these items may be eligible for a refund or a replacement (for example, if you receive the wrong item due to an Amazon AU error or if the item is faulty). In some cases, the nature of the item means that it is non-returnable, for example, due to hygiene/health and personal care/wellness/consumable nature of the product. You can return most new, unopened items fulfilled by Amazon AU within 30 days of receipt of delivery for a replacement or full refund of the price you paid for the item if you change your mind - see About Replacements and About Refunds. The reason BPA is so scary comes down to its ability to leach into packaged food and drinks. Think: eyewear, water bottles, and drink cans. But why is everyone concerned about BPA-free stuff anyway? Well, BPA (bisphenol A) is actually a chemical made for polycarbonate plastics and some metals. Using them in either may lead to cracking. The blender cups may be dishwasher-safe but they’re not safe for the microwave or the freezer. Motor base: Unplug and wipe clean with a warm soapy cloth as needed.Blade: Wash by hand with warm, soapy water as soon as you’re done using it.Here’s a breakdown of how to care for the pieces that come with your personal or full-size blender. Your nutribullet is well-made, and there are steps you can take to keep it in excellent condition. Nutribullet was acquired by home appliance giant De’Longhi in 2020. It’s evident that nutribullet is a hard-working appliance that pulls its own weight in the kitchen and for the price, it impresses many who buy it. Others say it crushes well and that the “ motor really gets it going.” Remarking on the convenience of the blender cup that turns into an actual cup, the 600W Nutrition Extractor turns out to be a well-loved item for making smoothies. This thing comes apart in 2 sections and cleanup is a breeze!” I used to have to take my old blender all apart to clean. “ I am amazed at the power of the motor, and the cleanup is easy. It turns out that the majority of customers report effortlessly smooth blending. Looking at the 600W Nutrition Extractor, we found an average of 4.5/5 stars from 1,303 shoppers. Do the majority of customers feel this way too? We headed over to Amazon to find out. Written by a team that tests the best of the best, the nutribullet blender is truly high-quality and rivals other, more expensive, models on the market. Of its performance, they reported “ silky-smooth smoothies and blended drinks, puréed nut butter with ease, and even ground hard cheeses without too much difficulty.” It’s a fantastic value option that holds its own with blenders that cost significantly more and we had a hard time finding any major issues with it.” It reads, the nutribullet 1200 watt blender “ is our top recommendation for anyone shopping for a new blender on a budget. Here’s what Gear Tech Lab’s team had to say about its overall use. Here’s how its overall score of 80/100 breaks down: The gadget review site put the nutribullet Blender to the test and ranked it at #5 on a list of 12 best blenders. Our next nutribullet review comes from Gear Tech Lab. Quality products are one thing, but quality staff that helps when needed is the difference between an ok company and a great brand. It’s nice when you find a company that does it all. Products and accessories powders supplements everything, and service has been very fast and helpful.” “ In all the years I’ve purchased from nutribullet everything has been better than expected. Baby Turbo Steamer: an average of 4.8/5 stars from 11 reviewsĭiving into the comments for the RX Cooking Blender, we found that a lot of customers love its size and say it’s very well made.Blender Combo: an average of 3.9/5 stars from 237 reviews.RX Cooking Blender: an average of 4.4/5 stars from 3,523 reviews.800W Juicer: an average of 4.2/5 stars from 608 reviews.After that, we’ll dive into the comments. Below you’ll find the ratings for some of the brand’s best-sellers. In this section of our nutribullet review, we’ll show you the results after a search for reliable feedback across the web. This one’s a crazy-popular brand, and like you, we want to know if it’s really worth all the hype. Free 1-years warranty for all blenders and juicers.Huge selection of blenders, juicers, and other appliances.What’s coming up in this nutribullet review? We’ll check out the brand’s highlights before whizzing up the details on its best-selling kitchen appliances. Today, the brand has 80 million happy customers and counting. Just like that, smoothies were changed forever. Since then, it has sold over 14 million units of the countertop-friendly blender, which is somehow even more powerful than its predecessor. The magic bullet was pretty successful, but it was the brand’s release of the nutribullet in 2012 that really brought it fame. The supercharged blender was impressively small, but magically made quick work of tough, tedious tasks. It claimed to blast through the walls of vegetables and fruits to release their full potential. 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The join method (called on a given string) can be used to concatenate a list of strings. Then use a file object to write every element of the list to the file as part of each loop iteration. We can convert the list to a single string then write it to disk in one shot. It requires data in a simpliest possible format: value_x1 value_y1įor now I always need to use Python to process a datafile created in Mathematica that format, because Mathematica always adds quotes " or multiple blank spaces or tabs. A common approach to write list elements to a file using Python is to first iterate through the elements of the list using a for loop. You can use the following syntax to export a pandas DataFrame to a text file: specify path for export path r'c:\datafolder\mydata.txt' export DataFrame to text file with open(path, 'a') as f: dfstring df.tostring(headerFalse, indexFalse) f. I am preparing data used by a command line program. The aesthetics of your new safe will be important if you’re planning on placing your safe out in the open. If you live far from a fire station, you may want to consider more than my minimum recommendation. I always suggest a minimum of 60 minutes of fire protection no matter the scenario. Fire protection is just as important as the safes strength and security features. You’ll also want to make sure that door includes several steel locking bolts that cover all four sides of the safes door, re-locker and a steel hard plate that prevents drilling. You’ll want to make sure that the boy of the safe you choose is made from thick steel, preferably a minimum thickness of 14-gauge. The strength and security features of your safe will decide how easy it is for an intruder to gain entry to your safe. A safe can be something you keep for a lifetime so it is best to always have the room available for expansion. My general rule of thumb when it comes to capacity is to always purchase a safe that you can grow into and not out of. When choosing the capacity of your new safe, it is important that you always leave room for expansion. If you’d like more in depth version of these features, check out my article “What to look for in a safe” In these next few paragraphs I’ll breakdown of each of these review categories. When reviewing a safe, I always make sure to touch on the most important features to look for in a safe: Capacity, fire protection, security, aesthetics and warranty. If you’re in the market for a gun safe and have had a chance to check out all of the different brands and features, you’ve probably realized that there is much more to a safe than just the aesthetics. Their full size FS series is the only full-size option from Fortress and provides 8 different sizing options to choose from. Their product catalogue includes small electronically locked home security safes, on the go mobile safes, nifty cash security boxes, heavy duty gun cabinets, pistol lock boxes and what we’ll be looking at for now, full-size gun safes. Fortress has also been an innovator in the safe world and has developed the first home security safe that allows for programmable alarm settings and a built in interior light.įortress has been intentional in designing a small variety of safes for your home, office, vehicle and more. I really believe that is why the Fortress name has really excelled in the gun safe world. You’ll find that Fortress has designed a great product with amazing value. Since then, The Fortress brand has been a go to for anyone looking for a light duty safe that is easier on the wallet than some of the other big names out there. Heritage safe company developed the Fortress brand over 20 years ago as a more affordable alternative to their higher end safes. Next, the movement took on a preppy look in the sporting items from brands like Polo, Timberland, and Tommy Hilfiger that spoke to the exclusivity and aspirational appeal of Hilfiger. They leaned towards top-of-the-line luxury brands and took to the factories to design create and manufacture their own. they had the money and influence to be taken seriously and so it is that they did two things. As the celebrities’ ‘bank’, the rappers, and producers knew the next step was to create their own fashion designs and fashion houses. The Hip Hop Fashion design opportunity created itself out of the demand. This is the generation that made it cool to wear athletic/sportswear, and athletic shoes to awards shows, onstage, and with tuxes. So here we are in 2023 and Hip Hop Fashion is recognized worldwide and can be considered the first in a long time that a culture emerged to shake up and create a whole new concept and approach to how people dressed. It was established as a real fashion category when designers like Karl Lagerfeld incorporated the influence at the House of Chanel. Mirroring The Rap/Hip Hop style the youth who listened to and grew up on the music increased the demand and fashion labels strictly designing for the Hip Hop/Rap generations were popping up and making money. As Hip Hop grew in affluence and money, the Hip Hop/ Rap fashion culture originated from Urban Black America and began to dominate the youths’ wardrobe. Feedback from our customers will help us to improve DefShop every day.It’s been 50 years since hip Hop hit the music sceneīlack people especially Black celebrities have always influenced and inspired street fashion so Hip Hop just took it to another level because of the emergence of a generation of Black wealth and with it-privilege.Īnd that’s the real story here. We would be happy, if you gave your feedback to us. We are available from Mondays up to Fridays between 10 a.m. Do you have special questions? Then please refer to our customer service. Dissatisfied? We grant a 30-day return policy with money-back guarantee. There you will also find the Returns Note which you can print out directly. There you will find answers to the frequently asked questions. If you have general questions about DefShop, try our help centre. We offer you the newest and trendy styles of the new season. What does that mean? If you find your favourite article in another store much cheaper, you can come back to us and we will sell this product for the same price and add a 10% discount on top. Shop cheap at DefShop with our low price guarantee From New Era, Nike, Dangerous DNGRS and Dickies to brands like Hurley and Karl Kani – we have a huge range of brands and products. We have even more brands you can look for. Our winter collection will take you easily through the winter season. But we don´t only have shoes, we also have the newest collections of Jeans, winter jackets, longsleeves and caps. For every different taste DefShop has something for you. We have Adidas shoes, Vans, Lacoste shoes, Hub shoes, Supra shoes and much more. Street wear for everyoneĭo you look for a new t-shirt, a new jeans or new sneakers? You are right here at DefShop. For certain you will find a new piece of clothing, which will be your new showpiece. Start now to look at our offers and products. Next to the most popular brands like Nike, Adidas or Jack & Jones you will find real rarities. About 20.000 articles and more than 200 brands are waiting for you. Here you get all what a street wear heart desires. If you are such a one who loves cool and casual styles and trends, then you´re right here at DefShop. The biggest online shop for street wear & Hip Hop in Europe There’ll be over 1,400 homes as part of the Rochester Riverside, which is really exciting. And being next to the station gives me a lot more chance in the future, if I were to move jobs. There’s a lot of regeneration being done in Medway. I work in Rochester so my new home will shorten my commute time. "This home is in such a nice area everything will be right on my doorstep. He was interested in the development since the start of the build in 2017. His one-bedroom apartment is close to the high street, train station, castle, cathedral and River Medway. " - Cathy Kinnon, moving into one of the shared ownership homesĬhris is also moving into one of the shared ownership homes. But our new home will be well suited to us for now and for the future as well. We’re so excited to be going into the next chapter of our lives into our first home that we own together. We don’t know what the future holds for me and my mobility which we were concerned about. "Where we live now is an old Victorian terrace with three floors and really steep stairs, so the idea of living in a ground floor flat was just so appealing. The pair viewed a show apartment at Corporation Street and immediately fell in love with the area and the fact they’d be able to move into a ground floor flat. It’s offered them a chance to downsize and prepare for the future in a new home they know will offer more security than privately renting. " - Hannah Wilson, Specialist in the Home Ownership and Supply team, at Homes EnglandĬathy and Ian Kinnon, both 53-years-old are due to move into one of the apartments at Corporation Street. We look forward to continuing our work in the South East to deliver more affordable homes in the future. This partnership is an excellent example of Homes England working with partners to deliver more homes faster, helping communities and providing affordable housing using funding from the Shared Ownership and Affordable Homes Programme. "It is wonderful to be working with mhs homes group in funding a high quality development, designed to meet the needs of local people. This development, backed by a £1.59 million grant from Homes England, is key to the regeneration of the centre of Rochester. One of the shared ownership blocks on site one The homes are ideally located for commuters, as they sit just next to the new train station. Since then we’ve worked to provide these high specification homes with contemporary interiors and private winter gardens. We secured planning permission in October 2016 and started redeveloping the site in January 2017. It was previously occupied by just 36 homes, built in the late 1920s and 1950s, which fell short of contemporary housing standards. The site provides 89 homes, 53 for shared ownership and 36 for rent. Rate shown with all applicable discounts and lowest term.We presented our development to The Worshipful the Mayor of Medway, Cllr Habib Tejan, local councillors and partners who helped throughout including Homes England, Chartway Group, bptw partnership, Currell part of the Savills Group, Churchill Hui and MOXY Property Consultants on Tuesday 18 June, to celebrate the development. Payment does not include applicable taxes and insurance. Auto debit discount of 0.25% APR and loan to value of less than 80% discount of 0.25% APR. Not all applicants will qualify for the lowest rate. Other rates subject to terms and are based on creditworthiness, therefore rates and terms may differ. *APR as low as = Annual Percentage Rate (APR). Effective 08-05-2023 Recreational Vehicle Type |
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